It doesn't work like that - you must have had faulty paste from the beginning, like an air pockets. In order to see such a big change.
If it makes it easier, see the paste as a thin layer of copper film. There is no heat stored in the paste as such, its just a pass through and with the Copper Heat Spreader standard today on chips you already have a big surface to work with.
But, as you said. There might be sloppy applications on the stock cards you get, and the paste you have on only works to 70-80%. Then checking and changing can be a big boost - and any paste you use will give good results.





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