It's common knowledge that Asus cannot make software. PC Probe is a crappy buggy essentially useless piece of junk. Temp warnings of CPU at 200*C, vcore at 50v, vdimm at 0.00v etc are common place. Uninstall it. Forget about it.

If you want to monitor voltages etc, AIDA64 (or cpuz for vcore) is popular and it actually works.

Go from there and see how you go.