Never believe software monitoring for your PSU, buy a multimeter and test it right! I always test new psu's prior to installing and usually again with the system live, just make sure that when you test you do it at idle and the hardest load you can put on the pc for cpu+gpu's.
Btw, Thermaltake psu's tend to fluctuate a lot on the 3.3v under a hard load if they are near their max rms output.
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