Intel still has not disclosed TjMax for 65nm desktop processors so all I can do is continue to guess.
Intel has stated that TjMax is 100C for an E8400. When I use that value, at higher temperatures where the amount of sensor error is minimal, the reported core temperature is approximately 5C greater than what an IR thermometer shows when pointed at the hottest spot on the IHS.
Using this new fact of life and working backwards, I have decided in the near future to start using TjMax=90C for the original B2, B3, the L2 and the E2xxx M0 series and probably a few others once I dig through the Intel specs some more. rge seems to agree that this is reasonable thinking based on Intel's published Thermal Specification for these processors.
Every program continues to assume that TjMax=85C for the original B2 but Intel has said that the logic behind that assumption is flawed because bit 30 in MSR 0xEE which is valid in the mobile processors to signal an 85C TjMax processor, is not relevant in the desktop processors. I'm getting ready to walk another plank and create some more controversy by introducing this never before used value in the near future.
I believe that the later E6x50 series are TjMax=100C like CoreTemp, Everest, etc. have been assuming for a long time.
RealTemp's original TjMax guesses were mostly based on IR thermometer testing. The new information released at IDF says that those numbers are too conservative and I should have added 5C to most processors.
Personally, I think that is a few degrees on the high side for the average processor but I've decided to more or less quietly comply with the small fragments of information provided to the user community from the guys in the blue suits.

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