Originally Posted by
SoulsCollective
As NetburstXE, disruptfam and myself have above pointed out, this advice is arse. You're correct in that the purpose of TIM is to improve heat transfer - no surface is ever completely flat right down at the microscopic level; what may be flat to the eye or the micrometer will in reality be covered in peaks and valleys. Therefore, you do not get perfect contact between the IHS and the baseplate, and therefore, thermal transfer is less efficient.
The purpose of TIM is to fill in these microscopic valleys, and thus increase the area of the two surfaces that is in contact - and thus increase thermal transfer. However, if you're ham-fisted in your application of TIM and smother the surfaces in contact, you'll actually decrease thermal transfer - no matter the product, TIM is less efficient at conducting heat than perfect metal-to-metal contact, and so it will actually serve as an insulator.
Apply sparingly in accordance with the manufacturers instructions and remember that the flatter the surfaces in contact the less TIM required and you'll be fine, but above all else do not listen to dnb#'s advice here.