You are right, the lower temperature doesn't do too much for the voltage needs of a CPU at a certain overclock. For example, mine can run 4Ghz at 1,45V on straight water as well.
But there is a temp threshold at which the CPU becomes unstable, that threshold gets lower the higher your OC is (and it's different and unique for each). For example, I need to stay below 60C coretemp if I want to prime 4Ghz or more. Which I can't hold 24/7 on water, and I don't get how you people manage to cool a quad at >1,6V and keep it under 60C. I always had a hard time doing that with even 1,45V, and I did have some badass wc setup.
Again, the reason must lie in the difference of CPUs. Some draw more amperes than others, with the low Vid chips usually being the ones with more leak currents, hence more heat dump than the high vid chips. Meaning that my Q6600 may well be eating the same amount of power at 1,45V as some high vid CPUs at 1,55-1,6V which is why you can run that kind of voltage in the first place.
If I would feed mine 1,6V my phase unit would go down and the PSU'd probably explode
Which is why I won't do it, problem is FSB anyway (stupid mobo won't go higher)
Old ones, L8XX sucks
Just remember guys, if you want 24/7 settings the old rule still applies.. max 1,45/1,5/1,55V air/water/phase.
Some might go beyond that, but I wouldn't give more than 1,6V 24/7 no matter what.
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