No, you can use 3 SATA hard drives with ICH7R without any issues, also you can use SATA DVD on JMicron. Simply native channels from ICH7R better supported by different OSs such as Linux, MacOS X, old and beta Windows versions, different live bootup CD/DVDs, bootup floppy disks and any standalone backup, partitioning and other programs working without OS. In this cases you have more chanches to access your DVD and 2 SATA hard drives. However really it is not a big chache not to access your DVD from JMicron, this controller is also widelly supported.
The only suggestion to stay away from EZ-backup while you have free other SATAs on board, EZ-backup connected through Silicon Image SATA controller to SATA4 port of ICH7R, resulting some reduced performance (not recommended for a system drive) and some problems with software I wrote above, but specially with diagnostic software.
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