Re: Re: Re: Aluminum Blocks
Quote:
Originally posted by chilly1
Forgot to mention aluminum will become stronger the colder it gets... It doesn't reach the glass stage til a lot closer to absolute zero.. And another supposition is that the thermal conductivity in a metal will radically change as temperature drops, due to the valence electrons dropping to a lower orbit. Where this happens I don't know but I intend to find out...
Not in metals, valence electrons ARE the lowest orbitals. For a metallic conductor conduction happens in the conduction band. There is no valanence coduction because electrons are held tightly into localized orbitals. So for conduction to occur an electron must escape into the conduction band (which is delocalized across the entire conductor and thus allows energy to travel at extremely high speed across macroscopic distances).
An electron is promoted to the conduction band by absorbing enough thermal energy to overcome the energy binding it into the valence band. This is why materials like LEDs that use semicoductor elements to create light vary the color of light produced with temperature. At low temperature very little energy is available so the smallest allowed jumps happened and you get lower frequency (low energy) light. At higher temps higher energy jumps are permitted and you can get higher freqency light. If you're ever bored dip a green LED into liquid nitrogen. It'll shift towards red. Get it cold enough and no electrons escape the valence band and it becomes a nonconductor.
Anyway this means that the coduction band is most effective at high temperatures . . . to a point. Thermal energy messes up the neat FCC stucture of most good conductors. As the structure is disturbed the conduction band is also distrubed which slows the flow of electrons (and thus heat riding on the electrons). Theres actually some ideal temperature for conduction that balances out these two effects in metals.
Note that i did not mention superconduction because Al and Cu have no super conductive properties at any temperature.
Re: Re: Re: Re: Aluminum Blocks
Quote:
Originally posted by saratoga
Not in metals, valence electrons ARE the lowest orbitals. For a metallic conductor conduction happens in the conduction band. There is no valanence coduction because electrons are held tightly into localized orbitals. So for conduction to occur an electron must escape into the conduction band (which is delocalized across the entire conductor and thus allows energy to travel at extremely high speed across macroscopic distances).
An electron is promoted to the conduction band by absorbing enough thermal energy to overcome the energy binding it into the valence band. This is why materials like LEDs that use semicoductor elements to create light vary the color of light produced with temperature. At low temperature very little energy is available so the smallest allowed jumps happened and you get lower frequency (low energy) light. At higher temps higher energy jumps are permitted and you can get higher freqency light. If you're ever bored dip a green LED into liquid nitrogen. It'll shift towards red. Get it cold enough and no electrons escape the valence band and it becomes a nonconductor.
Anyway this means that the coduction band is most effective at high temperatures . . . to a point. Thermal energy messes up the neat FCC stucture of most good conductors. As the structure is disturbed the conduction band is also distrubed which slows the flow of electrons (and thus heat riding on the electrons). Theres actually some ideal temperature for conduction that balances out these two effects in metals.
Note that i did not mention superconduction because Al and Cu have no super conductive properties at any temperature.
No...
http://www.allaboutcircuits.com/vol_1/chpt_12/6.html
http://sub.allaboutcircuits.com/images/10226.png
Quote:
The "alpha" (á) constant is known as the temperature coefficient of resistance, and symbolizes the resistance change factor per degree of temperature change. Just as all materials have a certain specific resistance (at 20o C), they also change resistance according to temperature by certain amounts. For pure metals, this coefficient is a positive number, meaning that resistance increases with increasing temperature
"meaning that resistance increases with increasing temperature"
most materials increase in resistance with increase in temperature. certain substances such as germanium and silicon decrease in resistance with increase in temperature.
Quote:
Originally posted by saratoga
Note that i did not mention superconduction because Al and Cu have no super conductive properties at any temperature.
please stop making up information. the critical temperature for Aluminum is 1.19K.
http://www.faqs.org/docs/electric/Ref/REF_3.html