The XSPC approach to cooling the VRMs should work just fine, IMO.
This barb will ensure that flow goes over the VRMs. "Path of least resistance" dictates it will take
all paths, which means over the VRMs (if that barb is aligned properly). I doubt that inlet vs. outlet will make much of a difference in end performance unless flowrates are so extraordinarily low that the heat from the VRMs increases the water temp noticeably before it gets to the core.
EDIT: and in case it's unclear, I don't think it matters much if that port is inlet or outlet when it comes to flow distribution (i.e., no observable thermal difference)--I skip that logical explanatory step above.